_0

Table 1 Crystal data and structure refinement for _0.
Identification code _0
Empirical formula ILi7S7Si2
Formula weight 456.08
Temperature/K 300.0
Crystal system monoclinic
Space group P21/n
a/Å 14.9520(2)
b/Å 6.04590(10)
c/Å 15.1634(2)
α/° 90
β/° 105.6940(10)
γ/° 90
Volume/Å3 1319.64(3)
Z 4
ρcalcg/cm3 2.296
μ/mm‑1 3.386
F(000) 856.0
Crystal size/mm3 0.03 × 0.02 × 0.02
Radiation synchrotron (λ = 0.6889)
2Θ range for data collection/° 3.29 to 72.266
Index ranges -25 ≤ h ≤ 25, -9 ≤ k ≤ 10, -25 ≤ l ≤ 25
Reflections collected 27518
Independent reflections 6436 [Rint = 0.0384, Rsigma = 0.0317]
Data/restraints/parameters 6436/44/236
Goodness-of-fit on F2 1.089
Final R indexes [I>=2σ (I)] R1 = 0.0272, wR2 = 0.0678
Final R indexes [all data] R1 = 0.0327, wR2 = 0.0710
Largest diff. peak/hole / e Å-3 1.10/-1.03

 

Table 2 Fractional Atomic Coordinates (×104) and Equivalent Isotropic Displacement Parameters (Å2×103) for _0. Ueq is defined as 1/3 of the trace of the orthogonalised UIJ tensor.
AtomxyzU(eq)
Si15847.3(3)3505.4(6)3913.0(2)19.03(7)
Si25801.7(2)3560.9(6)1505.9(2)18.74(7)
Li14962(2)9278(6)2471(2)46.7(7)
Li26896(3)7665(7)3039(3)55.2(14)
Li33448(4)2772(8)2138(4)53.8(16)
Li44711(8)8830(20)4615(8)55(4)
Li56682(12)8200(40)5326(11)57(6)
Li63416(7)3500(30)4492(8)57(5)
Li75932(5)3867(16)6200(5)51(3)
Li84849(7)-812(17)226(6)69(4)
Li96814(6)8040(20)529(6)47(2)
Li105855(5)3686(13)-754(4)45(2)
Li113260(7)3300(30)-344(9)60(5)
Li12500010000500082(12)
Li137015(13)8310(30)5107(11)43(4)
Li144320(30)-1830(80)660(30)43(12)
Li154290(20)7950(70)3940(30)73(9)
I13122.9(2)7431.4(2)1965.4(2)27.53(4)
S14522.5(3)2077.4(6)3660.3(3)25.32(7)
S26780.1(3)2439.2(6)5137.8(3)27.26(8)
S35742.5(3)6961.7(6)3886.8(3)26.57(7)
S46512.9(3)2317.1(5)2877.2(2)20.68(7)
S54459.1(3)2197.2(6)1102.9(3)23.74(7)
S66657.0(3)2369.9(6)719.6(3)25.91(8)
S75816.5(3)7024.9(6)1511.6(3)24.76(7)

 

Table 3 Anisotropic Displacement Parameters (Å2×103) for _0. The Anisotropic displacement factor exponent takes the form: -2π2[h2a*2U11+2hka*b*U12+…].
AtomU11U22U33U23U13U12
Si119.79(16)19.03(16)17.66(15)-0.85(12)4.05(12)-0.68(12)
Si219.68(16)18.56(16)17.65(15)-0.06(12)4.50(12)-0.79(12)
Li145.7(18)46.8(19)47.6(18)3.0(16)12.9(14)2.7(15)
Li231(2)92(4)38(2)2.1(16)2.4(18)-12.8(16)
Li353(3)63(3)51(3)11.8(19)23(2)16.8(19)
Li458(6)61(7)54(6)30(5)29(5)13(5)
Li549(7)79(14)41(7)-5(7)10(5)-13(7)
Li633(5)77(10)49(6)-34(6)-9(4)12(5)
Li750(5)67(6)41(4)4(4)20(3)24(4)
Li869(6)75(6)52(5)-25(4)-4(4)31(5)
Li939(4)55(6)55(4)7(4)23(3)3(4)
Li1041(4)59(5)33(3)5(3)6(3)14(3)
Li1141(5)84(11)64(7)41(7)30(4)13(5)
Li1287(15)78(12)82(13)12(8)25(7)3(7)
Li1337(7)58(10)26(6)2(6)-3(5)-6(7)
Li1437(14)50(15)45(14)0(9)16(9)11(8)
Li1553(12)94(16)75(9)3(11)22(6)27(8)
I122.84(6)29.46(6)29.47(6)-1.23(3)5.68(4)-1.32(3)
S120.44(16)26.54(15)28.75(17)-0.24(13)6.28(13)-3.42(12)
S224.54(19)36.9(2)18.43(16)1.32(12)2.48(13)4.50(12)
S332.10(19)19.03(14)28.59(17)-2.15(12)8.22(14)-0.21(13)
S420.37(16)23.19(15)17.83(14)0.42(10)4.03(11)2.96(10)
S519.18(16)25.43(15)24.62(16)-2.07(12)2.50(12)-3.16(11)
S625.33(19)32.45(19)21.35(16)-1.61(12)8.72(13)2.96(12)
S729.36(18)18.55(13)26.30(16)0.90(12)7.43(13)-1.50(12)

 

Table 4 Bond Lengths for _0.
AtomAtomLength/Å AtomAtomLength/Å
Si1S12.0990(5) Li6S322.456(11)
Si1S22.0996(5) Li7Li1253.057(10)
Si1S32.0951(5) Li7Li1521.15(4)
Si1S42.1953(5) Li7I122.868(7)
Si2S42.1963(5) Li7S122.568(9)
Si2S52.1022(5) Li7S22.460(7)
Si2S62.0977(5) Li7S322.521(8)
Si2S72.0944(5) Li8Li891.34(2)
Li1Li22.950(5) Li8Li952.932(12)
Li1Li313.037(6) Li8Li932.962(13)
Li1Li723.306(9) Li8Li1092.286(15)
Li1Li1033.124(8) Li8Li1193.166(14)
Li1Li1412.74(4) Li8Li1492.61(5)
Li1Li152.81(4) Li8Li141.31(4)
Li1I12.874(4) Li8S592.638(9)
Li1S112.682(4) Li8S52.416(8)
Li1S32.565(3) Li8S692.504(10)
Li1S412.891(4) Li8S752.465(9)
Li1S512.672(4) Li9Li103.354(15)
Li1S72.570(4) Li9Li1130.856(16)
Li2Li133.116(18) Li9Li1433.12(4)
Li2S32.450(4) Li9S242.592(8)
Li2S412.868(5) Li9S443.003(9)
Li2S642.460(4) Li9S532.687(9)
Li2S72.469(4) Li9S612.653(14)
Li3Li723.175(11) Li9S72.454(8)
Li3Li1033.354(9) Li10Li1132.58(2)
Li3I153.265(5) Li10Li13103.075(19)
Li3I12.859(4) Li10Li1491.17(5)
Li3I163.023(5) Li10I132.772(7)
Li3S12.466(6) Li10S532.562(8)
Li3S52.480(5) Li10S62.370(6)
Li4Li471.89(3) Li10S732.490(7)
Li4Li52.88(2) Li11Li13112.97(3)
Li4Li572.77(2) Li11Li1413.49(5)
Li4Li722.115(18) Li11S2122.550(9)
Li4Li120.943(15) Li11S52.519(10)
Li4Li151.18(4) Li11S632.687(18)
Li4Li1573.01(5) Li11S732.531(11)
Li4S122.614(11) Li12Li152.08(4)
Li4S112.409(9) Li12Li1572.08(4)
Li4S222.480(10) Li12S112.3301(4)
Li4S32.409(10) Li12S122.3301(4)
Li5Li621.08(2) Li12S213.0003(4)
Li5Li73.27(2) Li12S223.0003(4)
Li5Li1183.52(3) Li12S372.9104(4)
Li5Li122.66(2) Li12S32.9104(4)
Li5Li130.674(18) Li13I182.892(15)
Li5Li1573.10(4) Li13S212.52(2)
Li5I182.841(16) Li13S32.410(15)
Li5S122.670(19) Li13S642.68(2)
Li5S212.59(2) Li14I153.04(4)
Li5S32.375(15) Li14S52.52(5)
Li6Li722.27(2) Li14S692.22(4)
Li6Li1253.112(12) Li14S752.37(4)
Li6Li1321.48(3) Li15I13.05(4)
Li6Li153.20(5) Li15S112.57(4)
Li6I162.800(9) Li15S222.40(3)
Li6S12.488(11) Li15S32.28(3)
Li6S222.555(14)    

1+X,1+Y,+Z; 21-X,1-Y,1-Z; 31-X,1-Y,-Z; 43/2-X,1/2+Y,1/2-Z; 5+X,-1+Y,+Z; 61/2-X,-1/2+Y,1/2-Z; 71-X,2-Y,1-Z; 81/2+X,3/2-Y,1/2+Z; 91-X,-Y,-Z; 103/2-X,-1/2+Y,1/2-Z; 11-1/2+X,3/2-Y,-1/2+Z; 12-1/2+X,1/2-Y,-1/2+Z

 

Table 5 Bond Angles for _0.
AtomAtomAtomAngle/˚ AtomAtomAtomAngle/˚
S1Si1S2113.80(2) Li103Li11Li14114.1(7)
S1Si1S4108.84(2) Li103Li11S6353.5(4)
S2Si1S4102.19(2) Li1311Li11Si2396.7(6)
S3Si1S1110.17(2) Li1311Li11Li5116.9(6)
S3Si1S2110.57(2) Li1311Li11Li8152.6(5)
S3Si1S4111.03(2) Li1311Li11Li89157.2(8)
S5Si2S4108.70(2) Li1311Li11Li14163.7(8)
S6Si2S4101.95(2) Li141Li11Li51168.1(8)
S6Si2S5112.41(2) S212Li11Si23144.6(5)
S7Si2S4109.67(2) S212Li11Li51147.3(4)
S7Si2S5113.68(2) S212Li11Li8113.6(5)
S7Si2S6109.77(2) S212Li11Li89136.9(6)
Li2Li1Li31155.0(2) S212Li11Li103105.8(6)
Li2Li1Li7299.06(17) S212Li11Li131153.7(5)
Li2Li1Li103100.70(18) S212Li11Li141110.5(9)
Li31Li1Li7295.47(18) S212Li11S63109.0(5)
Li31Li1Li10398.88(19) S5Li11Si23109.0(4)
Li103Li1Li7292.7(2) S5Li11Li511106.5(6)
Li141Li1Li2105.3(8) S5Li11Li845.4(2)
Li141Li1Li3187.6(8) S5Li11Li8953.9(2)
Li141Li1Li72112.4(10) S5Li11Li10360.3(4)
Li141Li1Li10321.8(10) S5Li11Li1311109.0(7)
Li141Li1Li15128.5(13) S5Li11Li14173.3(8)
Li141Li1I165.5(9) S5Li11S21299.9(3)
Li141Li1S41114.5(9) S5Li11S63112.4(7)
Li15Li1Li2102.0(6) S5Li11S73101.2(3)
Li15Li1Li3185.3(7) S63Li11Si2341.03(17)
Li15Li1Li7219.5(8) S63Li11Li51163.2(5)
Li15Li1Li103110.7(9) S63Li11Li89112.6(4)
Li15Li1I164.9(8) S63Li11Li8134.4(4)
Li15Li1S41117.0(9) S63Li11Li131156.3(5)
I1Li1Li2137.82(16) S63Li11Li14139.6(7)
I1Li1Li3167.00(14) S73Li11Si2341.33(14)
I1Li1Li7254.78(15) S73Li11Li511141.7(6)
I1Li1Li10354.85(15) S73Li11Li869.1(4)
I1Li1S41163.38(14) S73Li11Li8949.8(3)
S11Li1Li2114.28(15) S73Li11Li103103.0(5)
S11Li1Li3150.62(12) S73Li11Li1311135.3(6)
S11Li1Li7274.90(17) S73Li11Li14195.9(8)
S11Li1Li103144.13(18) S73Li11S212150.0(8)
S11Li1Li141138.2(8) S73Li11S6382.1(3)
S11Li1Li1555.9(8) Li4Li12Li47180.0
S11Li1I191.90(10) Li47Li12Li5793.5(7)
S11Li1S4177.52(9) Li4Li12Li5786.5(7)
S3Li1Li252.19(10) Li47Li12Li586.5(7)
S3Li1Li31131.96(16) Li4Li12Li593.5(7)
S3Li1Li7248.90(14) Li47Li12Li15712.2(12)
S3Li1Li103111.80(18) Li4Li12Li157167.8(12)
S3Li1Li141131.6(9) Li47Li12Li15167.8(12)
S3Li1Li1550.1(6) Li4Li12Li1512.2(12)
S3Li1I1101.35(12) Li4Li12S1296.7(5)
S3Li1S1185.41(11) Li47Li12S1196.7(5)
S3Li1S4190.66(11) Li4Li12S1183.3(5)
S3Li1S51168.36(16) Li47Li12S1283.3(5)
S3Li1S790.08(11) Li4Li12S21131.4(6)
S41Li1Li258.80(11) Li47Li12S22131.4(6)
S41Li1Li3196.43(15) Li4Li12S2248.6(6)
S41Li1Li72131.98(19) Li47Li12S2148.6(6)
S41Li1Li103130.76(18) Li47Li12S3130.4(6)
S51Li1Li2119.56(15) Li4Li12S349.6(6)
S51Li1Li3151.00(11) Li4Li12S37130.4(6)
S51Li1Li72141.08(18) Li47Li12S3749.6(6)
S51Li1Li10376.57(16) Li57Li12Li5180.0
S51Li1Li14155.5(10) Li5Li12S2154.0(5)
S51Li1Li15136.1(6) Li57Li12S2254.0(5)
S51Li1I190.08(10) Li57Li12S21126.0(5)
S51Li1S1192.08(11) Li5Li12S22126.0(5)
S51Li1S4177.70(9) Li5Li12S37129.8(4)
S7Li1Li252.60(10) Li57Li12S3750.2(4)
S7Li1Li31137.45(17) Li5Li12S350.2(4)
S7Li1Li72112.65(18) Li57Li12S3129.8(4)
S7Li1Li10350.73(14) Li15Li12Li5780.7(9)
S7Li1Li14152.9(8) Li157Li12Li580.7(9)
S7Li1Li15129.8(8) Li157Li12Li5799.3(9)
S7Li1I1103.27(12) Li15Li12Li599.3(9)
S7Li1S11164.76(15) Li15Li12Li157180.0
S7Li1S4188.00(10) Li157Li12S1271.1(11)
S7Li1S5189.41(11) Li157Li12S11108.9(11)
Li1Li2Li1392.1(4) Li15Li12S12108.9(11)
S3Li2Li155.79(11) Li15Li12S1171.1(11)
S3Li2Li1349.6(4) Li15Li12S2252.6(9)
S3Li2S4193.59(14) Li15Li12S21127.4(9)
S3Li2S64100.62(14) Li157Li12S22127.4(9)
S3Li2S795.21(13) Li157Li12S2152.6(9)
S41Li2Li159.57(11) Li157Li12S3128.8(8)
S41Li2Li1385.3(4) Li15Li12S351.2(8)
S64Li2Li1146.84(19) Li15Li12S37128.8(8)
S64Li2Li1356.0(4) Li157Li12S3751.2(8)
S64Li2S41104.51(14) S11Li12Li5115.7(4)
S64Li2S7157.3(2) S12Li12Li564.3(4)
S7Li2Li155.77(10) S11Li12Li5764.3(4)
S7Li2Li13144.0(4) S12Li12Li57115.7(4)
S7Li2S4190.49(13) S12Li12S11180.000(13)
Li15Li3Li72105.6(2) S11Li12S2181.526(12)
Li15Li3Li103101.8(2) S12Li12S2198.474(12)
Li15Li3I1554.11(10) S11Li12S2298.474(12)
Li72Li3Li10390.8(2) S12Li12S2281.526(12)
Li72Li3I15134.5(2) S11Li12S3795.188(13)
I16Li3Li15120.85(16) S12Li12S3784.812(13)
I1Li3Li15143.3(2) S12Li12S395.188(13)
I1Li3Li7256.48(17) S11Li12S384.812(13)
I16Li3Li7277.39(18) S22Li12S21180.0
I16Li3Li103137.32(19) S3Li12S2183.119(11)
I1Li3Li10352.25(15) S37Li12S2283.120(11)
I15Li3Li103130.3(2) S3Li12S2296.881(11)
I1Li3I1688.53(13) S37Li12S2196.880(11)
I16Li3I1581.45(13) S3Li12S37180.000(12)
I1Li3I15161.6(2) Li2Li13Li490.7(4)
S1Li3Li1557.22(12) Li2Li13Li47111.6(5)
S1Li3Li7252.35(17) Li2Li13Li12101.3(4)
S1Li3Li103117.4(2) Li47Li13Li433.3(5)
S1Li3I1687.45(14) Li5Li13Li2129(2)
S1Li3I1107.8(2) Li5Li13Li4743(3)
S1Li3I1587.23(12) Li5Li13Li442(2)
S1Li3S5102.4(2) Li5Li13Li6242(3)
S5Li3Li1556.86(12) Li5Li13Li104134(2)
S5Li3Li72119.7(3) Li5Li13Li118141(3)
S5Li3Li10349.34(15) Li5Li13Li1240(3)
S5Li3I16162.9(3) Li5Li13I1879(2)
S5Li3I1585.07(13) Li5Li13S2188(3)
S5Li3I1101.43(16) Li5Li13S379(2)
Si12Li4Li15787.0(8) Li5Li13S64162(3)
Li47Li4Si1293.9(6) Li62Li13Li2114.0(9)
Li47Li4Li567.4(7) Li62Li13Li467.9(8)
Li47Li4Li5773.6(7) Li62Li13Li4783.6(10)
Li47Li4Li72177.7(8) Li62Li13Li104116.8(9)
Li47Li4Li1578.4(8) Li62Li13Li118166.7(10)
Li47Li4S1262.3(5) Li62Li13Li1275.1(9)
Li47Li4S1173.8(6) Li62Li13I1871.5(7)
Li47Li4S22114.8(7) Li62Li13S21130.1(12)
Li47Li4S3113.0(7) Li62Li13S374.0(8)
Li5Li4Si1297.1(5) Li62Li13S64119.6(12)
Li57Li4Si1285.3(5) Li104Li13Li295.9(6)
Li57Li4Li5141.0(6) Li104Li13Li4169.0(8)
Li5Li4Li15763.5(7) Li104Li13Li47135.7(7)
Li57Li4Li15777.8(7) Li104Li13Li12152.6(7)
Li72Li4Si1284.0(4) Li118Li13Li274.0(5)
Li72Li4Li57107.0(6) Li118Li13Li4123.9(7)
Li72Li4Li5111.9(6) Li118Li13Li47103.6(7)
Li72Li4Li157169.3(9) Li118Li13Li10450.5(5)
Li72Li4S12115.4(5) Li118Li13Li12114.7(7)
Li72Li4S11108.4(5) Li12Li13Li416.4(3)
Li72Li4S2264.2(4) Li12Li13Li4717.0(3)
Li72Li4S367.4(4) I18Li13Li2145.4(8)
Li12Li4Si1293.9(6) I18Li13Li47102.9(6)
Li12Li4Li470.0(7) I18Li13Li4121.1(7)
Li12Li4Li567.4(7) I18Li13Li10455.2(3)
Li12Li4Li5773.6(7) I18Li13Li11895.9(6)
Li12Li4Li72177.7(8) I18Li13Li12112.9(6)
Li12Li4Li1578.4(8) S21Li13Li2100.0(6)
Li12Li4Li15158(2) S21Li13Li476.7(5)
Li12Li4S1173.8(6) S21Li13Li4749.3(4)
Li12Li4S1262.3(5) S21Li13Li10493.4(6)
Li12Li4S22114.8(7) S21Li13Li11854.7(5)
Li12Li4S3113.0(7) S21Li13Li1262.8(4)
Li15Li4Si12104(2) S21Li13I18100.5(6)
Li15Li4Li47158(2) S21Li13S64110.1(7)
Li15Li4Li5121.6(16) S3Li13Li250.7(3)
Li15Li4Li5795.0(16) S3Li13Li446.2(4)
Li15Li4Li7224(2) S3Li13Li4777.8(6)
Li15Li4Li157166.5(14) S3Li13Li104143.5(8)
Li15Li4S12140(2) S3Li13Li118118.1(7)
Li15Li4S1184(2) S3Li13Li1261.5(4)
Li15Li4S2272.1(18) S3Li13I18145.1(9)
Li15Li4S369.6(15) S3Li13S21105.4(7)
S11Li4Si12146.6(4) S3Li13S6495.7(6)
S12Li4Si1243.85(14) S64Li13Li249.5(3)
S12Li4Li558.0(4) S64Li13Li4140.0(6)
S11Li4Li5761.6(5) S64Li13Li47153.5(7)
S12Li4Li57103.6(5) S64Li13Li10448.0(3)
S11Li4Li5105.9(6) S64Li13Li11856.6(5)
S11Li4Li15782.2(8) S64Li13Li12150.0(6)
S12Li4Li15753.9(8) S64Li13I1897.0(6)
S11Li4S12136.1(6) Li15Li14Li93112.9(14)
S11Li4S22112.3(4) Li15Li14Li115129.7(15)
S22Li4Si1244.50(14) Li15Li14Li1312111.5(13)
S22Li4Li5758.8(5) Li15Li14I1559.4(8)
S22Li4Li5140.7(5) Li8Li14Li15107(2)
S22Li4Li157112.5(8) Li89Li14Li15106.1(15)
S22Li4S1287.3(3) Li8Li14Li8910.9(11)
S3Li4Si12118.0(4) Li89Li14Li9360.9(9)
S3Li4Li57154.1(5) Li8Li14Li9371.1(18)
S3Li4Li552.5(4) Li8Li14Li115116(2)
S3Li4Li157112.4(7) Li89Li14Li115121.1(13)
S3Li4S12101.4(3) Li89Li14Li1312128.5(14)
S3Li4S1195.3(3) Li8Li14Li1312135(2)
S3Li4S22129.6(6) Li8Li14I15160(3)
Li47Li5Li439.0(6) Li89Li14I15150.7(17)
Li47Li5Li799.4(6) Li8Li14S570(2)
Li4Li5Li780.2(5) Li8Li14S6986(2)
Li4Li5Li118120.8(8) Li8Li14S7578.2(17)
Li47Li5Li118100.9(8) Li93Li14Li115105.0(11)
Li47Li5Li15722.2(7) Li93Li14Li131272.6(8)
Li4Li5Li15760.3(9) Li109Li14Li1598(2)
Li47Li5I18117.3(7) Li109Li14Li8134(3)
Li62Li5Li491.5(11) Li109Li14Li89143(3)
Li62Li5Li47116.8(13) Li109Li14Li93133(2)
Li62Li5Li718.6(9) Li109Li14Li11532.4(14)
Li62Li5Li118142.2(15) Li109Li14Li131262.6(17)
Li62Li5Li12104.4(12) Li109Li14I1565.8(18)
Li62Li5Li157120.8(15) Li109Li14S5154(3)
Li62Li5I1876.8(10) Li109Li14S6982(2)
Li62Li5S1268.6(11) Li109Li14S7582(2)
Li62Li5S21169.3(16) Li1312Li14Li11550.8(7)
Li62Li5S381.3(11) I15Li14Li9399.4(11)
Li7Li5Li118158.4(8) I15Li14Li11583.3(11)
Li12Li5Li419.1(3) I15Li14Li131252.7(7)
Li12Li5Li4719.9(3) S5Li14Li1560.9(9)
Li12Li5Li789.6(5) S5Li14Li8961.9(11)
Li12Li5Li118112.0(8) S5Li14Li9355.8(9)
Li12Li5Li15741.5(8) S5Li14Li115158.1(14)
Li12Li5I18132.3(7) S5Li14Li1312108.9(12)
Li12Li5S1251.8(4) S5Li14I1589.4(11)
Li13Li5Li47128(3) S69Li14Li15160.5(17)
Li13Li5Li4128(2) S69Li14Li8983.7(13)
Li13Li5Li62113(4) S69Li14Li9356.7(9)
Li13Li5Li7132(3) S69Li14Li11550.4(9)
Li13Li5Li11832(3) S69Li14Li131251.3(8)
Li13Li5Li12131(3) S69Li14I15104.0(14)
Li13Li5Li157125(3) S69Li14S5112.4(17)
Li13Li5I1888(2) S69Li14S75138.8(19)
Li13Li5S12174(2) S75Li14Li1559.9(9)
Li13Li5S2177(3) S75Li14Li8986.9(13)
Li13Li5S385(2) S75Li14Li93144.7(19)
Li157Li5Li7102.3(9) S75Li14Li115104.0(14)
Li157Li5Li11893.8(10) S75Li14Li1312142.6(18)
I18Li5Li4143.5(7) S75Li14I15103.7(14)
I18Li5Li778.5(5) S75Li14S597.8(15)
I18Li5Li11885.6(5) Li1Li15Li47100.2(13)
I18Li5Li15796.0(8) Li1Li15Li57111.9(14)
S12Li5Li456.1(4) Li1Li15Li6135.1(15)
S12Li5Li4752.6(4) Li1Li15Li137119.9(13)
S12Li5Li750.0(4) Li1Li15I158.6(7)
S12Li5Li118144.5(8) Li4Li15Li1109(2)
S12Li5Li15752.3(8) Li4Li15Li4713.5(14)
S12Li5I1887.6(5) Li4Li15Li5762.8(16)
S21Li5Li484.8(7) Li47Li15Li5756.2(8)
S21Li5Li4755.1(5) Li47Li15Li6120.9(12)
S21Li5Li7151.0(8) Li4Li15Li6109(2)
S21Li5Li11846.4(4) Li4Li15Li129.7(10)
S21Li5Li1269.7(6) Li4Li15Li13765.4(15)
S21Li5Li15748.8(8) Li47Li15Li13760.7(8)
S21Li5I18100.2(6) Li4Li15I1159(3)
S21Li5S12101.1(7) Li47Li15I1145.2(15)
S3Li5Li453.6(4) Li4Li15S1169(2)
S3Li5Li4788.3(6) Li4Li15S2280.1(18)
S3Li5Li786.4(6) Li4Li15S381.5(16)
S3Li5Li118101.6(6) Li57Li15Li6106.1(11)
S3Li5Li1270.4(4) Li57Li15Li1379.0(5)
S3Li5Li157110.4(10) Li6Li15Li13797.2(9)
S3Li5I18151.9(10) Li72Li15Li1106(2)
S3Li5S12100.7(6) Li72Li15Li47145(2)
S3Li5S21104.4(7) Li72Li15Li4131(3)
Si12Li6Li45112.3(4) Li72Li15Li57131(2)
Si12Li6Li4280.2(3) Li72Li15Li629.5(13)
Si12Li6Li12597.0(3) Li72Li15Li12141(3)
Si12Li6Li1567.2(8) Li72Li15Li137122.0(19)
Li42Li6Li4533.3(5) Li72Li15I170.2(18)
Li42Li6Li12517.5(3) Li72Li15S11160(3)
Li42Li6Li1596.5(7) Li72Li15S2279.5(19)
Li52Li6Si12114.5(11) Li72Li15S388.1(17)
Li52Li6Li4268.1(11) Li12Li15Li1102.8(16)
Li52Li6Li4546.6(11) Li12Li15Li473.8(4)
Li52Li6Li72152.7(14) Li12Li15Li5757.9(9)
Li52Li6Li12555.9(11) Li12Li15Li6117.5(15)
Li52Li6Li13224.7(13) Li12Li15Li13761.9(9)
Li52Li6Li15163.1(14) Li12Li15I1149.0(18)
Li52Li6I1681.1(9) Li12Li15S1159.0(11)
Li52Li6S187.5(12) Li12Li15S2283.9(13)
Li52Li6S22145.5(14) Li12Li15S383.5(13)
Li52Li6S3272.9(10) I1Li15Li57103.4(9)
Li72Li6Si1280.6(5) I1Li15Li690.3(11)
Li72Li6Li45107.4(5) I1Li15Li137103.7(8)
Li72Li6Li4294.0(5) S11Li15Li159.6(9)
Li72Li6Li125101.4(4) S11Li15Li4755.2(9)
Li72Li6Li1514.4(7) S11Li15Li5755.2(8)
Li72Li6I1699.3(5) S11Li15Li6160.8(12)
Li72Li6S165.2(4) S11Li15Li13764.1(9)
Li72Li6S2261.0(5) S11Li15I190.2(11)
Li72Li6S32112.0(5) S22Li15Li1158.6(14)
Li125Li6Li4515.9(2) S22Li15Li4785.4(11)
Li125Li6Li15107.5(6) S22Li15Li5754.4(7)
Li132Li6Si12102.8(8) S22Li15Li652.0(8)
Li132Li6Li4285.8(9) S22Li15Li13745.5(6)
Li132Li6Li4570.7(10) S22Li15I1105.7(12)
Li132Li6Li72176.5(10) S22Li15S11109.6(13)
Li132Li6Li12577.5(10) S3Li15Li159.5(8)
Li132Li6Li15169.1(11) S3Li15Li4784.4(12)
Li132Li6I1678.4(7) S3Li15Li57138.7(18)
Li132Li6S1112.1(11) S3Li15Li6104.4(13)
Li132Li6S22122.1(10) S3Li15Li137144.9(17)
Li132Li6S3270.6(8) S3Li15I1103.5(13)
Li15Li6Li45116.6(7) S3Li15S1194.1(14)
I16Li6Si12145.4(4) S3Li15S22142.0(17)
I16Li6Li42133.8(5) Li1I1Li3158.89(12)
I16Li6Li45100.8(4) Li1I1Li313131.14(12)
I16Li6Li125116.6(4) Li1I1Li1311125.1(4)
I16Li6Li15107.1(8) Li1I1Li14155.1(8)
S1Li6Si12118.0(4) Li1I1Li1556.5(7)
S1Li6Li4545.1(2) Li3I1Li1103.38(14)
S1Li6Li4254.4(3) Li3I1Li31399.20(15)
S1Li6Li12547.58(19) Li3I1Li31161.6(2)
S1Li6Li1577.6(7) Li313I1Li3190.79(13)
S1Li6I1692.2(3) Li3I1Li7267.3(2)
S1Li6S22125.1(7) Li3I1Li131188.5(4)
S22Li6Si1243.69(17) Li3I1Li14195.1(8)
S22Li6Li42119.0(5) Li313I1Li141161.6(8)
S22Li6Li45152.1(4) Li313I1Li1581.7(6)
S22Li6Li125136.3(4) Li3I1Li1588.5(8)
S22Li6Li1547.6(7) Li511I1Li1136.9(4)
S22Li6I16106.0(4) Li511I1Li31105.3(5)
S32Li6Si1243.97(15) Li511I1Li31384.5(4)
S32Li6Li4249.7(3) Li511I1Li391.0(5)
S32Li6Li4573.8(4) Li511I1Li72150.5(5)
S32Li6Li12561.7(3) Li511I1Li131113.5(4)
S32Li6Li15102.8(8) Li511I1Li14183.6(8)
S32Li6I16148.6(8) Li511I1Li15166.0(7)
S32Li6S1103.7(4) Li613I1Li1130.1(2)
S32Li6S2286.9(3) Li613I1Li3184.8(3)
Si12Li7Li1281.02(18) Li613I1Li3112.5(4)
Si12Li7Li3277.0(2) Li613I1Li31376.5(3)
Si12Li7Li587.1(4) Li613I1Li51122.1(5)
Li32Li7Li1287.9(2) Li613I1Li72155.9(3)
Li32Li7Li575.5(4) Li613I1Li131130.1(5)
Li42Li7Si1296.7(4) Li613I1Li14187.3(7)
Li42Li7Li1273.6(4) Li613I1Li15151.8(7)
Li42Li7Li32161.3(4) Li72I1Li170.30(19)
Li42Li7Li5122.2(5) Li72I1Li31379.71(18)
Li42Li7Li62117.2(5) Li72I1Li3199.8(2)
Li42Li7Li1250.7(2) Li72I1Li1311154.8(5)
Li42Li7I12112.5(4) Li72I1Li141116.8(7)
Li42Li7S12134.2(4) Li72I1Li1522.1(7)
Li42Li7S265.1(3) Li103I1Li167.17(17)
Li42Li7S3261.9(3) Li103I1Li313161.70(19)
Li5Li7Li12161.5(4) Li103I1Li31101.36(19)
Li62Li7Si1294.9(4) Li103I1Li373.11(19)
Li62Li7Li12169.0(4) Li103I1Li51179.1(4)
Li62Li7Li3281.2(4) Li103I1Li61390.9(3)
Li62Li7Li58.7(5) Li103I1Li72111.15(19)
Li62Li7Li125116.5(4) Li103I1Li131165.7(4)
Li62Li7I12118.7(4) Li103I1Li14122.6(9)
Li62Li7S1261.6(3) Li103I1Li15114.0(6)
Li62Li7S265.3(3) Li1311I1Li31105.4(4)
Li62Li7S32131.4(4) Li1311I1Li31398.0(4)
Li125Li7Si1296.6(2) Li1311I1Li14170.7(8)
Li125Li7Li1274.3(2) Li1311I1Li15176.9(8)
Li125Li7Li32161.8(3) Li141I1Li3178.8(9)
Li125Li7Li5121.5(4) Li141I1Li15110.4(10)
Li152Li7Si12106.8(15) Li15I1Li3177.7(8)
Li152Li7Li1254.8(18) Si1S1Li1589.50(8)
Li152Li7Li32140.1(19) Si1S1Li3116.38(13)
Li152Li7Li4224.8(19) Si1S1Li4276.5(2)
Li152Li7Li5143.2(19) Si1S1Li45105.9(3)
Li152Li7Li62136.1(18) Si1S1Li52132.1(3)
Li152Li7Li12525.5(19) Si1S1Li6119.3(3)
Li152Li7I1287.7(19) Si1S1Li7281.36(19)
Li152Li7S12149.4(15) Si1S1Li12590.633(17)
Li152Li7S273.2(16) Si1S1Li155122.3(7)
Li152Li7S3264.8(15) Li3S1Li1572.16(13)
I12Li7Si12112.9(2) Li3S1Li42166.1(3)
I12Li7Li1254.93(14) Li3S1Li52100.4(4)
I12Li7Li3256.19(17) Li3S1Li693.5(3)
I12Li7Li5118.7(4) Li3S1Li7278.2(2)
I12Li7Li125113.2(3) Li3S1Li155103.7(8)
S12Li7Si1242.65(11) Li45S1Li1583.1(3)
S12Li7Li12109.8(2) Li42S1Li15114.8(3)
S12Li7Li3249.48(18) Li45S1Li3130.0(4)
S12Li7Li552.8(4) Li45S1Li4243.9(6)
S12Li7Li125133.7(3) Li45S1Li5265.8(5)
S12Li7I12104.7(3) Li42S1Li5266.0(4)
S2Li7Si12137.7(3) Li45S1Li687.8(5)
S2Li7Li12124.2(3) Li45S1Li72135.9(3)
S2Li7Li32130.8(4) Li45S1Li15527.0(9)
S2Li7Li573.8(4) Li52S1Li15132.4(5)
S2Li7Li12564.8(2) Li6S1Li15151.2(3)
S2Li7I12109.4(2) Li6S1Li4274.8(3)
S2Li7S12125.7(3) Li6S1Li5223.9(5)
S2Li7S32125.2(4) Li6S1Li7253.3(5)
S32Li7Si1242.71(11) Li6S1Li15596.3(8)
S32Li7Li1250.04(16) Li72S1Li15140.93(18)
S32Li7Li32103.9(2) Li72S1Li4299.9(3)
S32Li7Li5125.7(4) Li72S1Li5277.2(5)
S32Li7Li12562.0(2) Li72S1Li155149.4(7)
S32Li7I12102.6(3) Li125S1Li1599.97(8)
S32Li7S1285.0(2) Li125S1Li3151.23(13)
Si29Li8Li11982.0(4) Li125S1Li4221.0(3)
Li89Li8Si2991.8(7) Li125S1Li4522.9(3)
Li89Li8Li9375.6(7) Li125S1Li5263.9(4)
Li89Li8Li9578.1(8) Li125S1Li680.4(4)
Li89Li8Li109169.8(10) Li125S1Li72117.91(16)
Li89Li8Li11987.6(8) Li125S1Li15549.9(9)
Li89Li8Li14910.7(10) Li155S1Li1564.5(8)
Li89Li8S5965.6(7) Li155S1Li4270.9(10)
Li89Li8S584.0(8) Li155S1Li5272.5(9)
Li89Li8S69110.9(8) Si1S2Li4279.6(2)
Li89Li8S75125.9(9) Si1S2Li55111.0(3)
Li95Li8Si2994.5(3) Si1S2Li6279.1(2)
Li93Li8Si2986.4(3) Si1S2Li797.73(17)
Li95Li8Li93153.7(5) Si1S2Li91091.5(2)
Li95Li8Li11915.5(3) Si1S2Li1114102.8(4)
Li93Li8Li119159.3(5) Si1S2Li12574.024(16)
Li109Li8Si2979.4(3) Si1S2Li135110.5(3)
Li109Li8Li9398.5(4) Si1S2Li15299.1(8)
Li109Li8Li95107.6(5) Li42S2Li5566.2(5)
Li109Li8Li11996.2(4) Li42S2Li6296.0(4)
Li109Li8Li149167.1(10) Li42S2Li910163.5(4)
Li109Li8S5100.2(4) Li42S2Li1114150.8(5)
Li109Li8S59109.8(4) Li42S2Li12516.6(3)
Li109Li8S6959.1(3) Li42S2Li13580.3(5)
Li109Li8S7563.1(3) Li55S2Li910104.9(5)
Li149Li8Si2988.7(9) Li55S2Li12556.3(4)
Li14Li8Si2994.5(19) Li62S2Li55156.2(5)
Li14Li8Li89158(2) Li62S2Li91096.0(5)
Li149Li8Li9568.1(9) Li62S2Li125109.6(3)
Li149Li8Li9385.6(9) Li7S2Li4250.7(4)
Li14Li8Li9384.1(17) Li7S2Li55102.7(5)
Li14Li8Li95121.9(18) Li7S2Li6253.7(4)
Li14Li8Li10921.5(19) Li7S2Li910145.3(4)
Li14Li8Li119113.7(18) Li7S2Li1114152.9(3)
Li149Li8Li11977.1(9) Li7S2Li12567.3(2)
Li14Li8Li149169.1(11) Li7S2Li135117.3(5)
Li149Li8S5957.4(10) Li910S2Li125147.0(2)
Li14Li8S59130(2) Li1114S2Li5586.4(6)
Li14Li8S579.0(19) Li1114S2Li62113.1(5)
Li14Li8S6962.3(17) Li1114S2Li91019.1(4)
Li14Li8S7570.3(17) Li1114S2Li125135.7(3)
S59Li8Si2942.76(12) Li135S2Li5515.1(4)
S5Li8Si29145.0(3) Li135S2Li62168.6(5)
S5Li8Li9358.9(3) Li135S2Li91089.9(6)
S59Li8Li9557.4(3) Li135S2Li111471.6(7)
S5Li8Li95118.3(4) Li135S2Li12568.8(4)
S59Li8Li93110.3(3) Li152S2Li4227.8(10)
S59Li8Li11950.5(3) Li152S2Li5576.8(11)
S5Li8Li119132.3(5) Li152S2Li6280.3(11)
S5Li8Li14992.4(9) Li152S2Li727.3(10)
S5Li8S59149.6(5) Li152S2Li910167.9(10)
S5Li8S69106.5(3) Li152S2Li1114156.1(9)
S5Li8S7598.2(3) Li152S2Li12543.6(10)
S69Li8Si2943.16(14) Li152S2Li13591.8(11)
S69Li8Li95135.1(4) Si1S3Li1125.11(8)
S69Li8Li9357.3(3) Si1S3Li297.09(11)
S69Li8Li119120.3(5) Si1S3Li4120.9(3)
S69Li8Li149114.7(9) Si1S3Li5105.9(6)
S69Li8S5985.4(2) Si1S3Li6281.6(4)
S75Li8Si29112.1(3) Si1S3Li7282.6(2)
S75Li8Li93149.1(4) Si1S3Li12131.055(19)
S75Li8Li9553.2(3) Si1S3Li13106.5(5)
S75Li8Li11951.6(2) Si1S3Li15109.1(11)
S75Li8Li149118.1(9) Li1S3Li1289.00(8)
S75Li8S5999.7(3) Li2S3Li172.02(12)
S75Li8S69119.8(5) Li2S3Li62107.6(3)
Li81Li9Li8326.3(5) Li2S3Li72146.80(19)
Li81Li9Li1080.9(3) Li2S3Li12128.88(11)
Li83Li9Li1092.1(3) Li4S3Li185.7(2)
Li83Li9Li14324.8(7) Li4S3Li2142.0(3)
Li81Li9Li14351.0(8) Li4S3Li6279.2(4)
Li83Li9S44145.4(5) Li4S3Li7250.7(4)
Li81Li9S44137.9(4) Li4S3Li1217.3(3)
Li113Li9Li83112.9(10) Li4S3Li1387.7(6)
Li113Li9Li8197.9(9) Li5S3Li1128.3(6)
Li113Li9Li1021.4(9) Li5S3Li295.9(5)
Li113Li9Li143120.4(13) Li5S3Li473.9(6)
Li113Li9S2477.7(8) Li5S3Li6225.8(5)
Li113Li9S4497.6(11) Li5S3Li72116.3(5)
Li113Li9S5369.6(9) Li5S3Li1259.4(5)
Li113Li9S61164.6(12) Li5S3Li1316.2(4)
Li113Li9S785.2(10) Li62S3Li1153.3(4)
Li143Li9Li1099.3(8) Li62S3Li72105.2(4)
S24Li9Li81148.9(4) Li62S3Li1270.3(2)
S24Li9Li83127.8(4) Li72S3Li181.07(18)
S24Li9Li1085.9(3) Li72S3Li1268.1(2)
S24Li9Li143104.4(8) Li13S3Li1122.9(5)
S24Li9S4473.0(2) Li13S3Li279.8(5)
S24Li9S5394.6(3) Li13S3Li6235.5(6)
S24Li9S61106.6(4) Li13S3Li72132.4(5)
S44Li9Li10119.0(4) Li13S3Li1271.7(5)
S44Li9Li143140.8(9) Li15S3Li170.5(10)
S53Li9Li8155.8(2) Li15S3Li2142.0(10)
S53Li9Li8350.4(2) Li15S3Li428.9(10)
S53Li9Li1048.6(2) Li15S3Li5102.5(11)
S53Li9Li14350.8(8) Li15S3Li62103.2(10)
S53Li9S44164.2(5) Li15S3Li7227.1(11)
S61Li9Li8170.6(3) Li15S3Li1245.2(11)
S61Li9Li8352.6(3) Li15S3Li13116.5(12)
S61Li9Li10143.2(4) Si1S4Si2111.61(2)
S61Li9Li14344.4(8) Si1S4Li1582.42(7)
S61Li9S4497.7(3) Si1S4Li25112.23(8)
S61Li9S5395.2(3) Si1S4Li91079.44(16)
S7Li9Li8153.6(3) Si2S4Li1581.99(7)
S7Li9Li8377.9(3) Si2S4Li25116.82(8)
S7Li9Li1085.5(4) Si2S4Li910142.8(2)
S7Li9Li143102.1(8) Li15S4Li910135.2(2)
S7Li9S24153.2(5) Li25S4Li1561.63(10)
S7Li9S4489.2(3) Li25S4Li91088.3(3)
S7Li9S5398.6(3) Si2S5Li1589.26(8)
S7Li9S6195.4(3) Si2S5Li3117.30(15)
Si23Li10Li1384.44(18) Si2S5Li895.8(3)
Si23Li10Li3376.59(18) Si2S5Li8978.8(2)
Si23Li10Li987.9(3) Si2S5Li93132.2(2)
Si23Li10Li1310148.7(5) Si2S5Li10377.67(16)
Li13Li10Li3387.9(2) Si2S5Li11123.2(3)
Li13Li10Li9160.5(3) Si2S5Li14117.5(8)
Li33Li10Li972.9(3) Li15S5Li93131.4(3)
Li89Li10Si2398.4(3) Li3S5Li1572.15(13)
Li89Li10Li1375.1(3) Li3S5Li89163.7(3)
Li89Li10Li33162.7(4) Li3S5Li93100.9(2)
Li89Li10Li9123.9(4) Li3S5Li10383.40(19)
Li89Li10Li113121.0(4) Li3S5Li1195.8(3)
Li89Li10Li1310111.6(5) Li3S5Li14106.4(9)
Li89Li10I13115.8(4) Li89S5Li15107.3(2)
Li89Li10S53137.3(4) Li8S5Li1582.6(3)
Li89Li10S665.0(3) Li8S5Li3137.1(3)
Li89Li10S7362.0(3) Li8S5Li8930.4(5)
Li113Li10Si2394.7(4) Li8S5Li9370.7(3)
Li113Li10Li13163.8(4) Li89S5Li9366.8(3)
Li113Li10Li3376.2(3) Li8S5Li103132.6(3)
Li113Li10Li97.0(3) Li8S5Li1186.7(5)
Li113Li10Li131062.6(5) Li8S5Li1430.8(9)
Li113Li10I13108.8(4) Li103S5Li15143.09(17)
Li1310Li10Li13111.2(4) Li103S5Li89103.8(3)
Li1310Li10Li3377.1(4) Li103S5Li9379.4(3)
Li1310Li10Li968.2(4) Li11S5Li15146.7(4)
Li149Li10Si23113.6(18) Li11S5Li8975.7(4)
Li149Li10Li1360.3(19) Li11S5Li9318.6(4)
Li149Li10Li33143.8(19) Li11S5Li10360.9(5)
Li149Li10Li8924.3(19) Li11S5Li1492.0(10)
Li149Li10Li9138.9(19) Li14S5Li1563.6(9)
Li149Li10Li113133.5(19) Li14S5Li8960.7(10)
Li149Li10Li131097.6(18) Li14S5Li9373.4(9)
Li149Li10I1391.6(19) Li14S5Li103152.3(9)
Li149Li10S53157.6(18) Si2S6Li21094.91(9)
Li149Li10S668.3(18) Si2S6Li8982.1(2)
Li149Li10S7370.5(18) Si2S6Li95119.11(17)
I13Li10Si23116.0(2) Si2S6Li10100.96(17)
I13Li10Li1357.98(14) Si2S6Li11381.8(3)
I13Li10Li3354.64(15) Si2S6Li1310146.6(4)
I13Li10Li9110.5(3) Si2S6Li149103.9(10)
I13Li10Li131059.0(4) Li210S6Li89159.1(3)
S53Li10Si2344.19(11) Li210S6Li9594.0(2)
S53Li10Li13112.1(2) Li210S6Li11390.6(3)
S53Li10Li3347.25(15) Li210S6Li131074.5(3)
S53Li10Li951.9(2) Li89S6Li9570.0(3)
S53Li10Li11358.7(3) Li89S6Li113109.3(4)
S53Li10Li1310104.7(5) Li89S6Li1310118.5(4)
S53Li10I13101.7(2) Li95S6Li113158.1(3)
S6Li10Si23135.4(3) Li95S6Li131093.5(5)
S6Li10Li13125.3(3) Li10S6Li210144.4(2)
S6Li10Li33129.9(3) Li10S6Li8955.9(3)
S6Li10Li971.9(3) Li10S6Li95105.4(3)
S6Li10Li11365.6(3) Li10S6Li11360.9(4)
S6Li10Li131057.2(4) Li10S6Li131074.8(4)
S6Li10I13108.3(2) Li1310S6Li11367.1(5)
S6Li10S53122.6(3) Li149S6Li210161.1(10)
S6Li10S73124.4(3) Li149S6Li8931.5(11)
S73Li10Si2344.34(11) Li149S6Li9578.9(12)
S73Li10Li1353.04(15) Li149S6Li1029.3(12)
S73Li10Li33105.3(2) Li149S6Li11390.0(12)
S73Li10Li9128.4(3) Li149S6Li131088.4(11)
S73Li10Li113134.1(4) Si2S7Li1121.74(8)
S73Li10Li1310163.3(5) Si2S7Li299.44(11)
S73Li10I13108.5(2) Si2S7Li81121.6(2)
S73Li10S5388.1(2) Si2S7Li9104.7(3)
Si23Li11Li511103.6(6) Si2S7Li10379.47(18)
Si23Li11Li8101.3(3) Si2S7Li11385.7(4)
Si23Li11Li8978.0(3) Si2S7Li141106.4(11)
Si23Li11Li14161.3(7) Li2S7Li171.63(13)
Li89Li11Li511158.2(7) Li2S7Li103141.22(18)
Li8Li11Li511147.9(5) Li2S7Li113109.1(3)
Li89Li11Li823.3(4) Li81S7Li183.7(2)
Li8Li11Li141107.8(7) Li81S7Li2138.9(2)
Li89Li11Li14194.9(7) Li81S7Li10355.0(3)
Li93Li11Si23115.0(11) Li81S7Li11378.6(3)
Li93Li11Li511128.8(10) Li9S7Li1133.5(3)
Li93Li11Li853.7(9) Li9S7Li2100.4(2)
Li93Li11Li8966.5(9) Li9S7Li8173.2(3)
Li93Li11Li103151.6(11) Li9S7Li103117.5(3)
Li93Li11Li1311134.0(11) Li9S7Li11319.7(3)
Li93Li11Li141161.1(12) Li103S7Li176.23(18)
Li93Li11S21283.2(9) Li103S7Li113109.5(4)
Li93Li11S591.9(10) Li113S7Li1152.4(4)
Li93Li11S63149.6(13) Li141S7Li167.2(10)
Li93Li11S7375.1(11) Li141S7Li2138.5(10)
Li103Li11Si2373.1(4) Li141S7Li8131.4(10)
Li103Li11Li51169.9(6) Li141S7Li9103.7(10)
Li103Li11Li898.7(4) Li141S7Li10327.7(11)
Li103Li11Li8990.3(4) Li141S7Li113104.8(10)
Li103Li11Li131167.0(6)     

1+X,1+Y,+Z; 21-X,1-Y,1-Z; 31-X,1-Y,-Z; 43/2-X,1/2+Y,1/2-Z; 5+X,-1+Y,+Z; 61/2-X,-1/2+Y,1/2-Z; 71-X,2-Y,1-Z; 81/2+X,3/2-Y,1/2+Z; 91-X,-Y,-Z; 103/2-X,-1/2+Y,1/2-Z; 11-1/2+X,3/2-Y,-1/2+Z; 12-1/2+X,1/2-Y,-1/2+Z; 131/2-X,1/2+Y,1/2-Z; 141/2+X,1/2-Y,1/2+Z

 

Table 6 Torsion Angles for _0.
ABCDAngle/˚ ABCDAngle/˚
Si11Li4Li12Li596.1(5) Li12Li4Li15S21-112(4)
Si11Li4Li12Li52-83.9(5) Li12Li4Li15S3101(4)
Si11Li4Li12Li15235(5) Li12Li5Li13Li2-54(5)
Si11Li4Li12Li15-145(5) Li12Li5Li13Li4-24.7(11)
Si11Li4Li12S13-148.4(3) Li12Li5Li13Li4225.5(15)
Si11Li4Li12S1131.6(3) Li12Li5Li13Li61-137(4)
Si11Li4Li12S23139.1(3) Li12Li5Li13Li108140.5(19)
Si11Li4Li12S21-40.9(3) Li12Li5Li13Li11963(4)
Si11Li4Li12S3122.7(6) Li12Li5Li13I19149(3)
Si11Li4Li12S32-57.3(6) Li12Li5Li13S2348(3)
Si11Li4Li15Li1-168.4(9) Li12Li5Li13S3-58(3)
Si11Li4Li15Li42144(5) Li12Li5Li13S68-133(6)
Si11Li4Li15Li5286.3(7) Li144Li8Li14Li15-89(5)
Si11Li4Li15Li6-12.6(14) Li144Li8Li14Li840.00(2)
Si11Li4Li15Li71-35(4) Li144Li8Li14Li9621(5)
Si11Li4Li15Li12144(5) Li144Li8Li14Li104152(3)
Si11Li4Li15Li13276.8(6) Li144Li8Li14Li115118(5)
Si11Li4Li15I1139(5) Li144Li8Li14Li13758(7)
Si11Li4Li15S13147.1(6) Li144Li8Li14I15-44(10)
Si11Li4Li15S2131.5(9) Li144Li8Li14S5-39(5)
Si11Li4Li15S3-115.1(7) Li144Li8Li14S6477(6)
Si24Li8Li14Li15165.1(13) Li144Li8Li14S75-142(5)
Si24Li8Li14Li84-106(5) Li15Li4Li12Li5261(5)
Si24Li8Li14Li96-85.9(4) Li152Li4Li12Li561(5)
Si24Li8Li14Li10446(4) Li152Li4Li12Li52-119(5)
Si24Li8Li14Li11511.9(17) Li15Li4Li12Li5-119(5)
Si24Li8Li14Li137-48(3) Li15Li4Li12Li152179.99(4)
Si24Li8Li14I15-151(6) Li152Li4Li12Li15-179.99(3)
Si24Li8Li14S5-145.3(4) Li15Li4Li12S13-4(5)
Si24Li8Li14S64-29.8(11) Li15Li4Li12S11176(5)
Si24Li8Li14S75111.9(7) Li152Li4Li12S11-4(5)
Li42Li4Li12Li570(54) Li152Li4Li12S13176(5)
Li42Li4Li12Li52-110(54) Li152Li4Li12S21-76(5)
Li42Li4Li12Li15-171(59) Li152Li4Li12S23104(5)
Li42Li4Li12Li1529(59) Li15Li4Li12S21104(5)
Li42Li4Li12S13-175(52) Li15Li4Li12S23-76(5)
Li42Li4Li12S115(52) Li15Li4Li12S3-92(5)
Li42Li4Li12S23113(52) Li152Li4Li12S388(5)
Li42Li4Li12S21-67(52) Li15Li4Li12S3288(5)
Li42Li4Li12S396(52) Li152Li4Li12S32-92(5)
Li42Li4Li12S32-84(52) Li152Li4Li15Li148(5)
Li42Li4Li15Li148(5) Li152Li4Li15Li420.00(2)
Li42Li4Li15Li52-57(4) Li152Li4Li15Li52-57(4)
Li42Li4Li15Li6-156(4) Li152Li4Li15Li6-156(4)
Li42Li4Li15Li71-179(2) Li152Li4Li15Li71-179(2)
Li42Li4Li15Li120.00(5) Li152Li4Li15Li120.00(4)
Li42Li4Li15Li132-67(4) Li152Li4Li15Li132-67(4)
Li42Li4Li15I1-4(10) Li152Li4Li15I1-4(10)
Li42Li4Li15S133(4) Li152Li4Li15S133(4)
Li42Li4Li15S21-112(4) Li152Li4Li15S21-112(4)
Li42Li4Li15S3101(4) Li152Li4Li15S3101(4)
Li42Li5Li13Li2-79(4) Li152Li5Li13Li2-107(3)
Li4Li5Li13Li2-29(6) Li152Li5Li13Li42-27.6(16)
Li4Li5Li13Li4250(2) Li152Li5Li13Li4-78(4)
Li42Li5Li13Li4-50(2) Li152Li5Li13Li61170(4)
Li4Li5Li13Li61-112(4) Li152Li5Li13Li10887(4)
Li42Li5Li13Li61-162(4) Li152Li5Li13Li11910(5)
Li4Li5Li13Li108165.2(11) Li152Li5Li13Li12-53(3)
Li42Li5Li13Li108115(3) Li152Li5Li13I1996(2)
Li42Li5Li13Li11938(5) Li152Li5Li13S23-5(2)
Li4Li5Li13Li11988(4) Li152Li5Li13S3-111(2)
Li4Li5Li13Li1224.7(11) Li152Li5Li13S68174(5)
Li42Li5Li13Li12-25.5(15) I19Li5Li13Li2158(3)
Li4Li5Li13I19173(3) I19Li5Li13Li42-123(2)
Li42Li5Li13I19123(2) I19Li5Li13Li4-173(3)
Li4Li5Li13S2372(3) I19Li5Li13Li6174.6(17)
Li42Li5Li13S2322(2) I19Li5Li13Li108-8(4)
Li4Li5Li13S3-34(3) I19Li5Li13Li119-86(3)
Li42Li5Li13S3-84(2) I19Li5Li13Li12-149(3)
Li4Li5Li13S68-108(7) I19Li5Li13S23-101.1(5)
Li42Li5Li13S68-158(6) I19Li5Li13S3152.9(7)
Li5Li4Li12Li52179.999(3) I19Li5Li13S6878(7)
Li52Li4Li12Li5180.001(3) S13Li4Li12Li5264.5(4)
Li5Li4Li12Li15119(5) S11Li4Li12Li564.5(4)
Li5Li4Li12Li152-61(5) S13Li4Li12Li5-115.5(4)
Li52Li4Li12Li15-61(5) S11Li4Li12Li52-115.5(4)
Li52Li4Li12Li152119(5) S11Li4Li12Li1524(5)
Li52Li4Li12S11115.5(4) S13Li4Li12Li154(5)
Li5Li4Li12S11-64.5(4) S13Li4Li12Li152-176(5)
Li52Li4Li12S13-64.5(4) S11Li4Li12Li15-176(5)
Li5Li4Li12S13115.5(4) S11Li4Li12S13180.000(3)
Li52Li4Li12S2143.0(6) S13Li4Li12S11180.000(3)
Li5Li4Li12S2343.0(6) S11Li4Li12S21-72.5(5)
Li52Li4Li12S23-137.0(6) S13Li4Li12S21107.5(5)
Li5Li4Li12S21-137.0(6) S11Li4Li12S23107.5(5)
Li5Li4Li12S32-153.4(6) S13Li4Li12S23-72.5(5)
Li5Li4Li12S326.6(6) S13Li4Li12S3-88.9(5)
Li52Li4Li12S3226.6(6) S13Li4Li12S3291.1(5)
Li52Li4Li12S3-153.4(6) S11Li4Li12S391.1(5)
Li52Li4Li15Li1105.3(13) S11Li4Li12S32-88.9(5)
Li5Li4Li15Li1-61(2) S13Li4Li15Li144.5(12)
Li52Li4Li15Li4257(4) S11Li4Li15Li1-137.0(16)
Li5Li4Li15Li42-109(5) S11Li4Li15Li42175(6)
Li5Li4Li15Li52-166.0(16) S13Li4Li15Li42-3(4)
Li52Li4Li15Li6-99.0(11) S11Li4Li15Li52118(2)
Li5Li4Li15Li695.0(16) S13Li4Li15Li52-60.8(6)
Li52Li4Li15Li71-121(3) S11Li4Li15Li619(3)
Li5Li4Li15Li7173(4) S13Li4Li15Li6-159.8(11)
Li52Li4Li15Li1257(4) S11Li4Li15Li71-4(5)
Li5Li4Li15Li12-109(5) S13Li4Li15Li71178(3)
Li5Li4Li15Li132-175.6(17) S11Li4Li15Li12175(6)
Li52Li4Li15Li132-9.5(5) S13Li4Li15Li12-3(4)
Li52Li4Li15I153(6) S13Li4Li15Li132-70.3(5)
Li5Li4Li15I1-113(5) S11Li4Li15Li132108(2)
Li5Li4Li15S13-105.2(14) S11Li4Li15I1171(4)
Li52Li4Li15S1360.8(6) S13Li4Li15I1-8(5)
Li5Li4Li15S21139.1(11) S11Li4Li15S13178.6(18)
Li52Li4Li15S21-54.9(9) S13Li4Li15S21-115.7(6)
Li5Li4Li15S3-7(2) S11Li4Li15S2163(2)
Li52Li4Li15S3158.6(8) S13Li4Li15S397.8(8)
Li61Li5Li13Li283(4) S11Li4Li15S3-84(2)
Li61Li5Li13Li4112(4) S21Li4Li12Li5137.0(6)
Li61Li5Li13Li42162(4) S21Li4Li12Li52-43.0(6)
Li61Li5Li13Li108-83(4) S21Li4Li12Li15276(5)
Li61Li5Li13Li119-160(2) S21Li4Li12Li15-104(5)
Li61Li5Li13Li12137(4) S21Li4Li12S13-107.5(5)
Li61Li5Li13I19-74.6(17) S21Li4Li12S1172.5(5)
Li61Li5Li13S23-175.7(16) S21Li4Li12S23180.0
Li61Li5Li13S378.3(17) S21Li4Li12S32-16.4(9)
Li61Li5Li13S684(9) S21Li4Li12S3163.6(9)
Li71Li4Li15Li1-133(4) S21Li4Li15Li1160.1(18)
Li71Li4Li15Li42179(2) S21Li4Li15Li42112(4)
Li71Li4Li15Li52121(3) S21Li4Li15Li5254.9(9)
Li71Li4Li15Li622(2) S21Li4Li15Li6-44.1(8)
Li71Li4Li15Li12179(2) S21Li4Li15Li71-67(3)
Li71Li4Li15Li132112(3) S21Li4Li15Li12112(4)
Li71Li4Li15I1175(9) S21Li4Li15Li13245.3(8)
Li71Li4Li15S13-178(3) S21Li4Li15I1108(6)
Li71Li4Li15S2167(3) S21Li4Li15S13115.7(7)
Li71Li4Li15S3-80(3) S21Li4Li15S3-146.5(13)
Li7Li5Li13Li285(4) S23Li5Li13Li2-101(3)
Li7Li5Li13Li42165(4) S23Li5Li13Li42-22(2)
Li7Li5Li13Li4114(4) S23Li5Li13Li4-72(3)
Li7Li5Li13Li612.3(8) S23Li5Li13Li61175.7(16)
Li7Li5Li13Li108-80(4) S23Li5Li13Li10893(3)
Li7Li5Li13Li119-157.8(19) S23Li5Li13Li11915(3)
Li7Li5Li13Li12139(4) S23Li5Li13Li12-48(3)
Li7Li5Li13I19-72(2) S23Li5Li13I19101.1(5)
Li7Li5Li13S23-173(2) S23Li5Li13S3-106.1(5)
Li7Li5Li13S381(2) S23Li5Li13S68180(7)
Li7Li5Li13S686(9) S3Li4Li12Li52153.4(6)
Li84Li8Li14Li15-89(5) S3Li4Li12Li5-26.6(6)
Li84Li8Li14Li9621(5) S3Li4Li12Li152-88(5)
Li84Li8Li14Li104152(3) S3Li4Li12Li1592(5)
Li84Li8Li14Li115118(5) S3Li4Li12S1388.9(5)
Li84Li8Li14Li13758(7) S3Li4Li12S11-91.1(5)
Li84Li8Li14I15-44(10) S3Li4Li12S21-163.6(9)
Li84Li8Li14S5-39(5) S3Li4Li12S2316.4(9)
Li84Li8Li14S6477(6) S3Li4Li12S32180.000(1)
Li84Li8Li14S75-142(5) S3Li4Li15Li1-53.3(9)
Li96Li8Li14Li15-109.0(15) S3Li4Li15Li42-101(4)
Li95Li8Li14Li1567(2) S3Li4Li15Li52-158.6(8)
Li96Li8Li14Li84-21(5) S3Li4Li15Li6102.5(14)
Li95Li8Li14Li84155(6) S3Li4Li15Li7180(3)
Li95Li8Li14Li96176.0(11) S3Li4Li15Li12-101(4)
Li95Li8Li14Li104-52(5) S3Li4Li15Li132-168.1(7)
Li96Li8Li14Li104132(4) S3Li4Li15I1-105(6)
Li96Li8Li14Li11597.8(16) S3Li4Li15S13-97.8(8)
Li95Li8Li14Li115-86.2(19) S3Li4Li15S21146.5(13)
Li96Li8Li14Li13738(3) S3Li5Li13Li25(3)
Li95Li8Li14Li137-146(2) S3Li5Li13Li4284(2)
Li96Li8Li14I15-65(6) S3Li5Li13Li434(3)
Li95Li8Li14I15111(6) S3Li5Li13Li61-78.3(17)
Li95Li8Li14S5116.6(12) S3Li5Li13Li108-161(3)
Li96Li8Li14S5-59.4(4) S3Li5Li13Li119122(3)
Li95Li8Li14S64-128.0(10) S3Li5Li13Li1258(3)
Li96Li8Li14S6456.0(9) S3Li5Li13I19-152.9(7)
Li96Li8Li14S75-162.3(9) S3Li5Li13S23106.1(5)
Li95Li8Li14S7513.7(19) S3Li5Li13S68-74(7)
Li104Li8Li14Li15119(5) S54Li8Li14Li15139.3(12)
Li104Li8Li14Li84-152(3) S5Li8Li14Li15-49.6(13)
Li104Li8Li14Li96-132(4) S54Li8Li14Li84-132(6)
Li104Li8Li14Li115-34(3) S5Li8Li14Li8439(5)
Li104Li8Li14Li137-94(5) S54Li8Li14Li96-111.7(15)
Li104Li8Li14I15164(10) S5Li8Li14Li9659.4(4)
Li104Li8Li14S5169(4) S54Li8Li14Li10420(5)
Li104Li8Li14S64-76(4) S5Li8Li14Li104-169(4)
Li104Li8Li14S7566(4) S54Li8Li14Li115-14(3)
Li119Li5Li13Li2-117(5) S5Li8Li14Li115157.2(18)
Li119Li5Li13Li42-38(5) S54Li8Li14Li137-74(4)
Li119Li5Li13Li4-88(4) S5Li8Li14Li13797(3)
Li119Li5Li13Li61160(2) S5Li8Li14I15-5(6)
Li119Li5Li13Li10877(4) S54Li8Li14I15-176(5)
Li119Li5Li13Li12-63(4) S54Li8Li14S5-171.1(13)
Li119Li5Li13I1986(3) S5Li8Li14S64115.4(11)
Li119Li5Li13S23-15(3) S54Li8Li14S64-56(2)
Li119Li5Li13S3-122(3) S54Li8Li14S7586.0(16)
Li119Li5Li13S68164(10) S5Li8Li14S75-102.9(8)
Li114Li8Li14Li1581.9(19) S64Li8Li14Li15-165(2)
Li114Li8Li14Li84170(6) S64Li8Li14Li84-77(6)
Li114Li8Li14Li96-169.1(8) S64Li8Li14Li96-56.0(9)
Li114Li8Li14Li104-38(5) S64Li8Li14Li10476(4)
Li114Li8Li14Li115-71.3(19) S64Li8Li14Li11541.8(11)
Li114Li8Li14Li137-131(2) S64Li8Li14Li137-18(2)
Li114Li8Li14I15126(6) S64Li8Li14I15-121(7)
Li114Li8Li14S5131.5(9) S64Li8Li14S5-115.4(11)
Li114Li8Li14S64-113.0(10) S64Li8Li14S75141.7(15)
Li114Li8Li14S7528.7(15) S75Li8Li14Li1553.3(11)
Li12Li4Li15Li148(5) S75Li8Li14Li84142(5)
Li12Li4Li15Li420.00(3) S75Li8Li14Li96162.3(9)
Li12Li4Li15Li52-57(4) S75Li8Li14Li104-66(4)
Li12Li4Li15Li6-156(4) S75Li8Li14Li115-99.9(18)
Li12Li4Li15Li71-179(2) S75Li8Li14Li137-160(4)
Li12Li4Li15Li132-67(4) S75Li8Li14I1598(6)
Li12Li4Li15I1-4(10) S75Li8Li14S5102.9(8)
Li12Li4Li15S133(4) S75Li8Li14S64-141.7(15)

11-X,1-Y,1-Z; 21-X,2-Y,1-Z; 3+X,1+Y,+Z; 41-X,-Y,-Z; 5+X,-1+Y,+Z; 61-X,1-Y,-Z; 7-1/2+X,1/2-Y,-1/2+Z; 83/2-X,1/2+Y,1/2-Z; 91/2+X,3/2-Y,1/2+Z

 

Table 7 Atomic Occupancy for _0.
AtomOccupancy AtomOccupancy AtomOccupancy
Li30.900(16) Li40.373(14) Li50.320(18)
Li60.370(17) Li70.493(15) Li80.469(14)
Li90.53(2) Li100.503(13) Li110.47(2)
Li120.12(2) Li130.239(13) Li140.098(15)
Li150.173(16)     

Experimental

Single crystals of ILi7S7Si2 [_0] were []. A suitable crystal was selected and [] on a dectris-CrysAlisPro-abstract goniometer imported dectris images diffractometer. The crystal was kept at 300.0 K during data collection. Using Olex2 [1], the structure was solved with the SHELXT [2] structure solution program using Intrinsic Phasing and refined with the SHELXL [3] refinement package using Least Squares minimisation.

  1. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H. (2009), J. Appl. Cryst. 42, 339-341.
  2. Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.
  3. Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.

Crystal structure determination of [_0]

Crystal Data for ILi7S7Si2 (=456.08 g/mol): monoclinic, space group P21/n (no. 14), a = 14.9520(2) Å, b = 6.04590(10) Å, c = 15.1634(2) Å, β = 105.6940(10)°, = 1319.64(3) Å3, Z = 4, T = 300.0 K, μ(synchrotron) = 3.386 mm-1, Dcalc = 2.296 g/cm3, 27518 reflections measured (3.29° ≤ 2Θ ≤ 72.266°), 6436 unique (Rint = 0.0384, Rsigma = 0.0317) which were used in all calculations. The final R1 was 0.0272 (I > 2σ(I)) and wR2 was 0.0710 (all data).

Refinement model description

Number of restraints - 44, number of constraints - unknown.

Details:

1. Uiso/Uaniso restraints and constraints
Uanis(Li8) ≈ Ueq, Uanis(Li12) ≈ Ueq, Uanis(Li14) ≈ Ueq: with sigma
of 0.01 and sigma for terminal atoms of 0.02
2. Rigid body (RIGU) restrains
Li4, Li7, Li12, Li15, S3, S2
with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
Li5, Li6, Li13, S3
with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
3. Others
1*[Sof(Li3)]+1*[Sof(Li4)]+1*[Sof(Li5)]+1*[Sof(Li6)]+1*[Sof(Li7)]+1*[Sof(Li8)]+
1*[Sof(Li10)]+1*[Sof(Li12)]+1*[Sof(Li13)]+1*[Sof(Li14)]+1*[Sof(Li15)]=4 with
esd of 0.001
1*[Sof(Li9)]+1*[Sof(Li11)]=1 with esd of 0.001

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